Synthesis and characterization of a ruthenium-containing copolymer for use as a photoredox catalyst-Reference-Cited by-同舟云学术

Synthesis and characterization of a ruthenium-containing copolymer for use as a photoredox catalyst

Published:2023 Issue:39 Volume:14 Page:4560-4568
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Huss Steven¹,Walsh Andrew R.²,Griggs Anna¹,Rodriguez-Acevedo Diego Alejandro¹,Arias-Rotondo Daniela M.²^ORCID,Elacqua Elizabeth¹³^ORCID

Affiliation:

1. Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA

2. Department of Chemistry and Biochemistry, Kalamazoo College, Kalamazoo, Michigan 49006, USA

3. Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802, USA

Abstract

We present a [Ru(bpy)2(dmbpy)]2+- and pyrene-based photocatalytic PMMA that enables photoredox-energy transfer to achieve the C–H arylation of electron deficient aryl bromides.

Funder

Pennsylvania State University

National Science Foundation

Alfred P. Sloan Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2023/PY/D3PY00428G

Reference55 articles.

1. Triplet Energy Transfer Photocatalysis: Unlocking the Next Level

2. Energy transfer catalysis mediated by visible light: principles, applications, directions

3. Mechanistic Analysis of Metallaphotoredox C–N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity

4. Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II)

5. Improved Visible Light Absorption of Potent Iridium(III) Photo-oxidants for Excited-State Electron Transfer Chemistry

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