Visible-light-mediated Diels–Alder reactions under single-chain polymer confinement: investigating the role of the crosslinking moiety on catalyst activity-Reference-Cited by-同舟云学术

Visible-light-mediated Diels–Alder reactions under single-chain polymer confinement: investigating the role of the crosslinking moiety on catalyst activity

Published:2024 Issue:18 Volume:15 Page:1833-1838
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Spicuzza Michael¹,Gaikwad Shweta Prakesh¹,Huss Steven¹,Lee Annemarie A.²,Craescu Cristina V.¹,Griggs Anna¹,Joseph Joshmi¹,Puthenpurayil Mark¹,Lin Wilson¹,Matarazzo Christopher¹,Baldwin Stanley¹³,Perez Victoria²,Rodriguez-Acevedo Diego Alejandro¹,Swierk John R.²^ORCID,Elacqua Elizabeth¹^ORCID

Affiliation:

1. Department of Chemistry, The Pennsylvania State University, University Park PA, 16802, USA

2. Department of Chemistry, State University of New York at Binghamton, Vestal, NY 13850, USA

3. Department of Natural, Health, and Mathematical Sciences, MidAmerica Nazarene University, Olathe, KS, 66062, USA

Abstract

Single-chain polymer nanoparticle photoredox catalysts are designed wherein spatial proximity enables the crosslinking acene to act as a redox mediator, thus achieving up to 30-fold enhancement of catalyst activity in the model Diels–Alder reaction.

Funder

National Science Foundation

National Institutes of Health

Alfred P. Sloan Foundation

Pennsylvania State University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/PY/D4PY00282B

Reference43 articles.

1. Single‐chain polymers as homogeneous oxidative photoredox catalysts

2. CO 2 ‐Folded Single‐Chain Nanoparticles as Recyclable, Improved Carboxylase Mimics

3. Organic Photoredox-Catalyzed Cycloadditions Under Single-Chain Polymer Confinement

4. Amphiphilic Polymeric Nanoparticles for Photoredox Catalysis in Water

5. Single-Chain Nanoparticle Delivers a Partner Enzyme for Concurrent and Tandem Catalysis in Cells

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