Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex-Reference-Cited by-同舟云学术

Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex

Published:2020 Issue:6 Volume:11 Page:1607-1616
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Nicolay Amélie¹²³⁴⁵^ORCID,Ziegler Micah S.¹²³⁴⁵^ORCID,Small David W.¹²³⁴,Grünbauer Rebecca⁶⁷⁸⁹,Scheer Manfred⁶⁷⁸⁹^ORCID,Tilley T. Don¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of California, Berkeley

3. Berkeley

4. USA

5. Chemical Sciences Division

6. Institut für Anorganische Chemie

7. Universität Regensburg

8. 93040 Regensburg

9. Germany

Abstract

A dicopper complex featuring a symmetrically bridging nitrile ligand and supported by a binucleating naphthyridine-based ligand was treated with phosphaalkynes to yield dicopper complexes that exhibit phosphaalkynes in rare μ-η²:η² binding modes.

Funder

Division of Graduate Education

Link Foundation

National Institutes of Health

Basic Energy Sciences

Fulbright Association

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC05835D