Combining metal–metal cooperativity, metal–ligand cooperativity and chemical non-innocence in diiron carbonyl complexes-Reference-Cited by-同舟云学术

Combining metal–metal cooperativity, metal–ligand cooperativity and chemical non-innocence in diiron carbonyl complexes

Published:2022 Issue:7 Volume:13 Page:2094-2104
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

van Beek Cody B.¹,van Leest Nicolaas P.²^ORCID,Lutz Martin³,de Vos Sander D.¹,Klein Gebbink Robertus J. M.¹^ORCID,de Bruin Bas²^ORCID,Broere Daniël L. J.¹^ORCID

Affiliation:

1. Organic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Faculty of Science, Utrecht University Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands

2. Homogeneous, Supramolecular and Bio-Inspired Catalysis Group, Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

3. Structural Biochemistry, Bijvoet Centre for Biomolecular Research, Faculty of Science, Utrecht University Universiteitsweg 99, 3584 CG, Utrecht, The Netherlands

Abstract

The PNNP expanded pincer ligand can bind two iron centers in close proximity and display heterolytic and homolytic metal–ligand cooperativity.

Funder

Netherlands Organisation for Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC05473B

Reference113 articles.

1. Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase