One-Pot, Yet Two-Step, Hydrotitanation of 1-Silyl- or 1-Stannyl-1-alkynes, Showing the Opposite Regioselectivity to the Routine Hydrometalations

Author:

Urabe Hirokazu1,Hamada Takashi1,Sato Fumie1

Affiliation:

1. Department of Biomolecular Engineering Tokyo Institute of Technology, 4259 Nagatsuta-cho Midori-ku, Yokohama, Kanagawa 226-8501, Japan

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference23 articles.

1. Weber, W. P.Silicon Reagents for Organic Synthesis; Springer-Verlag:  Berlin, 1983; p 98. Colvin, E. W.Silicon in Organic Synthesis; Butterworth:  London, 1981; p 45.

2. Smith, K.; Pelter, A. InComprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press:  Oxford, 1991; Vol. 8, p 703. Pelter, A.; Smith, K.; Brown, H. C.Borane Reagents; Academic Press:  London, 1988; p 98.

3. Sato, F.; Urabe, H. InHandbook of Grignard Reagents; Silverman, G. S., Rakita, P. E., Eds.; Marcel Dekker:  New York, 1996; p 23. Wakefield, B.Organomagnesium Methods in Organic Synthesis; Academic Press:  London, 1995; p 54. Sato, F.J. Organomet. Chem.1985,285, 53.

4. Hydroalumination of CC and CC

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