Affiliation:
1. School of Chemistry and Chemical Engineering Shandong University of Technology 266 West Xincun Road Zibo 255049 P. R. China
Abstract
AbstractHerein, we report a palladium/norbornene/copper co‐catalyzed single‐step approach that merges selective ortho C−H bond esterification with ipso thiolation for construction of synthetically versatile 2‐arylthio aryl esters under exceptionally mild conditions. Importantly, this process proceeded in a highly efficient manner, allowing alkoxycarbonyl and thio groups to be installed into one aryl iodides simultaneously by harnessing thiocarbonate as bifunctional reagent. The method has been demonstrated to accommodate good functionalities and features broad substrate scope.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Shandong Province
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Cited by
1 articles.
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