Metal-free C(sp3)-H Bromination: Synthesis of Phenacyl bromide and Benzyl bromide derivatives

Author:

Mal Sourav,Sarkar Satinath,Jana ManoranjanORCID

Funder

Department of Science & Technology and Biotechnology, Government of West Bengal

Publisher

Springer Science and Business Media LLC

Subject

General Chemistry

Reference24 articles.

1. (a) Shilov A E and Shul'pi G B 1997Activation of C-H Bonds by Metal Complexes Chem. Rev. 97 2879; (b) Labinger J A and Bercaw J E 2002 Understanding and exploiting C–H bond activation Nature 417 507; (c) Godula K and Sames D 2006 C-H Bond Functionalization in Complex Organic Synthesis Science 312 67; (d) Lafrance M, Gorelsky S I and Fagnou K 2007 High-Yielding Palladium-Catalyzed Intramolecular Alkane Arylation: Reaction Development and Mechanistic Studies J. Am. Chem. Soc. 129 14570; (e) Delord J W, Droge T, Liu F and Glorius F 2011 Towards mild metal-catalyzed C–H bond activation Chem. Soc. Rev. 40 4740; (f) Yamaguchi J, Yamaguchi A D and Itami K 2012 CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals Angew. Chem. Int. Ed. 51 8960

2. Zhang C, Li Z L, Gu Q S and Liu X Y 2021 Catalytic enantioselective C(sp3)–H functionalization involving radical intermediates Nat. Commun. 12 475

3. (a) Sathyamoorthi S, Banerjee S, Bois J D, Burns N Z and Zare R N 2018 Site-selective bromination of sp3 C-H bonds Chem. Sci. 9 100

4. (b) Kee C W, Chan K M, Wong M W and Tan C H 2014 Selective Bromination of sp3 C-H Bonds by Organophotoredox Catalysis Asian J. Org. Chem. 3 536

5. Macharla A K, Nappunni R C, Marri M R, Peraka S and Nama N 2012 Oxidative bromination of ketones using ammonium bromide and oxone Tetrahedron Lett. 53 191

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