Site-selective bromination of sp3 C–H bonds
Author:
Affiliation:
1. Stanford University
2. Department of Chemistry
3. Stanford
4. USA
5. Indian Institute of Science Education and Research Tirupati
6. Tirupati-517507
7. India
Abstract
A method for converting sp3 C–H to C–Br bonds using an N-methyl sulfamate directing group is described. For all sulfamates examined, bromination occurs with high selectivity at the γ-carbon, affording a predictable method for C–H bond halogenation.
Funder
Division of Chemistry
Air Force Office of Scientific Research
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04611A
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