Thermo-Oxidative Stability Studies of Celion 6000/PMR-15 Unidirectional Composites, PMR-15, and Celion 6000 Fiber

Author:

Bowles Kenneth J.1,Nowak Gregory1

Affiliation:

1. National Aeronautics and Space Administration Lewis Research Center Cleveland, Ohio 44135

Abstract

Studies were conducted to examine the influence of the thermo-oxidative resistance characteristics of the fiber and matrix resin on the thermal stability of composites made from these materials. Celion 6000 graphite fiber, PMR-15 matrix resin, and Celion 6000/PMR-15 unidirectional composites were isothermally aged in air-circulating ovens at 288, 316, 329, and 343 °C. Microscopy (SEM) studies indicate extreme oxidative erosion of the graphite fiber occurs at elevated temperatures in the presence of the polyimide matrix. Activation energies were calculated for the thermal degradation of the three materials. The activation energy of oxidation of the composite was found to be greater than those of the fiber and the matrix resin.

Publisher

SAGE Publications

Subject

Materials Chemistry,Mechanical Engineering,Mechanics of Materials,Ceramics and Composites

Reference13 articles.

1. Thermally stable polyimides from solutions of monomeric reactants

2. Hanson, M.P. and T.T. Serafini. in Space Shuttle Materials, 3:31-38, SAMPE (1971).

3. The oxidation of carbon fibres in air between 230° and 375°C

4. Burns, E.A., R.J. Jones, R.W. Vaughan and W.P. Kendrick. "Thermally Stable Laminating Resins," NASA CR-72633, pp. 63-68 (1970).

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