An eco-friendly epoxy polymer binder for the treatment of Tunisian harbor sediments: Laboratory investigations for beneficial reuse

Abstract

The management of dredged sediments poses serious environmental and economic problems because of their geochemical properties and in particular their pollutant content. In this research, marine sediments from Tunisian harbors were collected to study their beneficial reuse as construction materials using an eco-friendly polymer binder. Experimental investigations include the determination of physicochemical, mineralogical, and environmental parameters of sediments from the Sidi Mansour and Sidi Youssef areas in Tunisia. Prismatic mortar samples (4 × 4 × 16 cm) were prepared at laboratory scale using normalized sand and epoxy resin. Then their composition was modified by including a sediment fraction in the substitution of sand at rates ranging from 10 to 50% in dry mass. After a 7-day curing period, mortar samples were submitted to mechanical, physicochemical, and environmental analyses. Mortar samples including sediment fractions displayed lower strength than sand mortar used as control. This result is explained by the increase of porosity values in the mortar samples when sediment samples were incorporated. A positive relationship between porosity and compressive strength values was evidenced, suggesting that the compactness of granular skeleton could play an important role in the preparation of materials. From an environmental point of view, the mortar samples containing sediment fractions showed relatively low leaching levels, which confirms their suitability for the manufacturing of construction materials.