Solid-state foaming of poly(ether-ether-ketone)/hydroxyapatite composites

Author:

Zhu Hanyu1,Morquecho Enrique Velasquez1,Li Wei1ORCID

Affiliation:

1. Walker Department of Mechanical Engineering, The University of Texas at Austin, Austin, TX, USA

Abstract

Poly(ether-ether-ketone) (PEEK) is a high strength and high temperature-resistant plastic with good potential for medical use. The addition of hydroxyapatite (HA) can improve the mechanical performance and biocompatibility of PEEK. However, little study has been done on solid-state foaming of PEEK or PEEK-based composites due to the semicrystalline nature and high processing temperature requirement. In this study, the solid-state foaming behavior of PEEK/HA composite is studied using supercritical [Formula: see text]. A quenching process is applied to reduce the crystallinity and improve the gas saturation behavior. The mechanical properties of foamed PEEK/HA composite are characterized. The results show that quenching substantially improved the foamability of PEEK/HA composite. Foamed PEEK/HA regained crystallinity and exhibit a compressive strength comparable to human trabecular bone.

Funder

John T. MacGuire Endowment

Walker Department of Mechanical Engineering, The University of Texas at Austin

Publisher

SAGE Publications

Subject

Materials Chemistry,Polymers and Plastics,General Chemistry

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