CATION AND ANION ELECTRONIC EXCITATIONS IN MgO AND BaF2 CRYSTALS UNDER EXCITATION BY PHOTONS UP TO 75 eV

Author:

KIRM M.1,VIELHAUER S.1,ZIMMERER G.1,LUSHCHIK A.2,LUSHCHIK Ch.2

Affiliation:

1. II. Institut für Experimentalphysik der Universität Hamburg Luruper Chaussee 149, Hamburg 22 761, Germany

2. Institute of Physics, University of Tartu, Riia 142, Tartu 51 014, Estonia

Abstract

The creation of primary and secondary cation excitations was investigated for MgO and BaF 2 crystals using the energy-and time-resolved luminescence method. It was shown that the primary cation excitations in MgO created by photons of 50–65 eV decay with the formation of anion free excitons and electron–hole pairs. The formation of secondary cation holes by hot photoelectrons in the Ba 2+ 5p shell causes the increase of cross-luminescence intensity whereas the creation of neither primary nor secondary cation excitons causes the appearance of cross-luminescence in BaF 2.

Publisher

World Scientific Pub Co Pte Lt

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics

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