Characterization and Applications of Calcium Ferrites Based Materials Containing Active Oxygen Species

Author:

Hirabayashi Daisuke1,Yoshikawa Takeshi1,Kawamoto Yoshiki1,Mochizuki Kazuhiro1,Suzuki Kenzi1

Affiliation:

1. EcoTopia Science Institute

Abstract

Characterization and application of calcium ferrites based solid solutions containing active oxygen species for catalysts in propylene total and methane partial oxidation has been studied. The calcium ferrite based solutions containing brownmillerite phases showed a structural transition based on the migration of oxide ions at high temperature. The calcium ferrite solution provided two types of active oxygen species due to the existence of the brownmillerite phase. These oxygen species individually played important roles in the propylene and methane oxidation mechanisms.

Publisher

Trans Tech Publications Ltd

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