Author:
Dedyukhin Alexander S.,Shchetinskiy Andrey V.,Kharina Ekaterina A.,Shchepin Ivan E.,Volkovich Vladimir A.,Yamshchikov Leonid F.,Osipenko Alexandr G.
Abstract
The behavior and properties of lanthanum in a “molten salt – liquid metal” system in relation to pyrochemical reprocessing of spent nuclear fuels was considered. Temperature dependencies of lanthanum formal standard electrode potential E*
La/La(III) and Gibbs free energy change of lanthanum trichloride formation in LiCl–KCl–CsCl eutectic based melts were obtained between 668–976 K. Also the behavior of lanthanum was studied in Ga–Al (1.6 wt. % Al) and Ga–Zn (3.64 wt. % Zn) eutectic based metallic alloys, and activity, solubility and activity coefficients of lanthanum determined.
Publisher
The Electrochemical Society
Cited by
11 articles.
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