Heat-resistant binders based on oligomeric organosilsesquioxanes-Reference-Cited by-同舟云学术

Heat-resistant binders based on oligomeric organosilsesquioxanes

Published:2022-05-23 Issue:3-4 Volume: Page:5-10
ISSN:0554-2901
Container-title:Plasticheskie massy
language:
Short-container-title:Plastičeskie massy

Author:

KIREEV V. V.¹,BILICHENKO YU. V.¹,BREDOV N. S.¹

Affiliation:

1. Dmitry Mendeleev University of Chemical Technology of Russia

Abstract

The influence of the phase state of the reaction system and the HCl concentration during hydrolytic polycondensation of methyltrichlorosilane on the composition of the formed oligomers, their stability during storage and ability to thermal curing is shown. The technological production process is developed and the scheme of a pilot plant for obtaining oligomethylsilsesquioxanes used for the production of highly filled thermo- and fire-resistant polymer composite materials is presented.

Publisher

Publishing House Plastic Ltd

Subject

Polymers and Plastics,Chemical Engineering (miscellaneous)

Reference16 articles.

1. Fina A., Tabuani D., Carniato F., Frache A., Boccaleri E., Camino G. Polyhedral oligomeric silsesquioxanes (POSS) thermal degradation // Thermochimica Acta. 2006. V. 440(1). P. 36–42. https://doi.org/10.1016/j.tca.2005.10.006.

2. Liu L., Zhang W., Yang R. Flame retardant epoxy composites with epoxy‐containing polyhedral oligomeric silsesquioxanes // Polymers for Advanced Technologies. 2020. V. 31. №9. P. 2058–2074. https://doi.org/10.1002/pat.4929.

3. Jothibasu S., Chandramohan A., Kumar A. A., Alagar M. Polyhedral oligomeric silsesquioxane (POSS) reinforced-unsaturated polyester hybrid nanocomposites: Thermal, thermomechanical and morphological properties // Journal of Macromolecular Science. Part A. 2018. V. 55(5). P. 433–439. https://doi.org/10.1080/10601325.2018.1453264.

4. Qi Z., Zhang W., He X., Yang R. High-efficiency flame retardency of epoxy resin composites with perfect T8 caged phosphorus containing polyhedral oligomeric silsesquioxanes (P-POSSs) // Composites Science and Technology. 2016. V. 127. P. 8-19. https://doi.org/10.1016/j.compscitech.2016.02.026.

5. Laine R.M., Roll M.F. Polyhedral phenylsilsesquioxanes // Macromolecules. 2011. V. 44(5). P. 1073–1109. https://doi.org/10.1021/ma102360t.