The Conductivity Enhancement of 1.5Li2O-P2O5 Solid Electrolytes by Montmorillonite Addition

Author:

Purwamargapratala Yustinus12ORCID,Syahrial Anne Zulfia1ORCID,Putra Teguh Yulius Surya Panca2ORCID,Kartini Evvy2ORCID,Jodi Heri2ORCID

Affiliation:

1. Department of Metallurgy and Materials Engineering, University of Indonesia, UI Depok Campus, West Java 16424, Indonesia

2. National Research and Innovation Agency (BRIN), Puspiptek National Science Technopark, South Tangerang, Banten 15314, Indonesia

Abstract

Most solid electrolyte materials have not shown enough conductivity to be used as an electrolyte for a battery in electronic devices. The mixture of 1.5 Li2O and P2O5 has been reported to show a good conductivity higher than that of Li3PO4, which is thought to be due to phase mixtures that are formed during manufacturing process. Montmorillonite (MMT) was used to explore the effect of phase mixture on conductivity of new 1.5Li2O-P2O5-MMT solid electrolyte composite, which was prepared through conventional solid-state reaction procedures. This study was conducted, how the addition of MMT affects process of forming 1.5Li2O-P2O5-MMT compound, and whether it influences electrical properties and permittivity of compound. Morphology, hygroscopicity, and electrochemical characteristics of this material were analyzed in this study. The shape of glassy-like flakes was reduced in micrographs, and granular lumps were getting larger as MMT was added. Addition also tended to reduce hygroscopicity, as indicated by a reduced rate of porous absorption. Whole Nyquist plot consisted of only one imperfect semicircular arc, indicating only one relaxation process occurred in materials. Capacitance of all arcs indicated main contribution of response was from bulk material. Slope of dielectric loss of samples indicated that conduction in the samples was mainly dominated by dc conduction. MMT clays acted as a medium that absorbed liquid phase in solid-state reaction, increasing formation of dominant phase, which determined total conductivity of compound. Conductivity was higher than that of Li4P2O7, where the sample of 20 wt% MMT addition was most polarizable and most dielectric compound.

Funder

University of Indonesia

Publisher

Institute of Research and Community Services Diponegoro University (LPPM UNDIP)

Subject

Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Environmental Engineering,Energy (miscellaneous)

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