Vibrational and Electronic Energy Levels of Polyatomic Transient Molecules. Supplement A

Abstract

A summary is presented of recently published, critically evaluated experimental vibrational and electronic energy level data for neutral and ionic transient molecules and high temperature species possessing from three to sixteen atoms. Although the emphasis is on species with lifetimes too short for study using conventional sampling techniques, there has been selective extension of the compilation to include data for isolated molecules of inorganic species such as the heavy-metal oxides, which are important in a wide variety of industrial chemical systems. Radiative lifetimes and the principal rotational constants are included. Observations in the gas phase, in molecular beams, and in rare-gas and diatomic molecule matrices are evaluated. The types of measurement surveyed include conventional and laser-based absorption and emission techniques, laser absorption with mass analysis, and photoelectron spectroscopy. Not counting isotopic species, 904 molecules are surveyed, and 2696 distinct references are given.