Time-resolved Raman spectroscopy for monitoring the structural evolution of materials during rapid compression

Author:

Chen XiaoHui12ORCID,Zhang Yi1ORCID,Ye Shijia1ORCID,Li Shourui1,Liu Lei1,Jing Qiuming1ORCID,Gao Junjie1,Wang Hao3ORCID,Lin Chuanlong3,Li Jun1ORCID

Affiliation:

1. National Key Laboratory of Shock Wave and Detonation Physics 1 , Mianyang 621900, Sichuan, China

2. United Laboratory of High-Pressure Physics and Earthquake Science 2 , Mianyang 621900, Sichuan, China

3. Center for High Pressure Science and Technology Advanced Research 3 , Beijing 100094, China

Abstract

Rapid compression experiments performed using a dynamic diamond anvil cell (dDAC) offer the opportunity to study compression rate-dependent phenomena, which provide critical knowledge of the phase transition kinetics of materials. However, direct probing of the structure evolution of materials is scarce and so far limited to the synchrotron based x-ray diffraction technique. Here, we present a time-resolved Raman spectroscopy technique to monitor the structural evolutions in a subsecond time resolution. Instead of applying a shutter-based synchronization scheme in previous work, we directly coupled and synchronized the spectrometers with the dDAC, providing sequential Raman data over a broad pressure range. The capability and versatility of this technique are verified by in situ observation of the phase transition processes of three rapid compressed samples. Not only the phase transition pressures but also the transition pathways are reproduced with good accuracy. This approach has the potential to serve as an important complement to x-ray diffraction applied to study the kinetics of phase transitions occurring on time scales of seconds and above.

Funder

the United Laboratory of High-Pressure Physics and Earthquake Science

the Foundation of National Key Laboratory of Shock Wave and Detonation

Publisher

AIP Publishing

Subject

Instrumentation

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