Boron clusters: Do they receive the deserved interest?

Author:

Teixidor Francesc1,Viñas Clara1,Demonceau Albert1,Nuñez Rosario1

Affiliation:

1. 1Institut de Ciència de Materials de Barcelona (CSIC), Campus U.A.B., E-08193 Bellaterra, Spain

Abstract

New applications in which the carborane and metallacarborane species play a crucial role have been recently developed. In these applications, clusters display many particular characteristics that do not find parallel in their organic counterparts. The o-carborane can modulate the C···C distances depending on the substituents bonded to the cluster carbon atom and can lead to the formation of uncommon halogenophosphane charge-transfer “spoke ” complexes with iodine due to their electron-withdrawing capacity. Besides, metallacarboranes have been used as doping agents in organic conducting polymers and as catalysts in Kharasch reactions.

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry

Reference6 articles.

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4. et al Pure and Steric Effects in Metallacarboranes in Metal Clusters in Chemistry New York;Lewis;Organomet Chem Chem Soc Dalton Trans Chem Applied Chemistry,1992

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