CHARACTERIZATION OF TRACE ELEMENTS AND LIGHT ABSORBING PARTICLES (LAPs) AT SNOW OF HUAYTAPALLANA GLACIER (PERU)

Abstract

This study reports for the first time the content of trace elements and light-absorbing particles (LAPs) in snow samples collected from a Peruvian glacier (Huaytapallana). The sampling campaign was carried out monthly from November 2015 to March 2019. The trace elements content was quantified by inductively coupled plasma mass spectrometry, while LAPs were analyzed using the light absorption heating method. The chemical composition dataset was assessed by descriptive statistics and t-test for assessing dry season and wet season differences. In addition, enrichment factor (EF) and hierarchical cluster analysis (HCA) were employed to identify possible emission sources. The snow, ice, and aerosol radiative (SNICAR) model was used to measure the effect of LAPs on snow albedo and radiative forcing (RF). Based on analysis of EF and HCA, it was shown that Al, Ti, Si, Co, Ce, Sr, Mn, Mg, Ba and Na have mainly natural sources; K, Ca, Fe, Cu, Pb and As have a mixture of natural and anthropogenic sources, and Zn has anthropogenic source. SNICAR model results indicated that LAPs reduced the snow albedo by up 4.5 % in the dry season with RF values as high as 33 W/m2. Therefore, we conclude that the presence of these particles substantially increases melt or sublimation rates of Peruvian glaciers.