Affiliation:
1. Ural Federal University
2. I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Abstract
Azaheterocyclic derivatives of 1,2-dicarba-closo-dodecaborane (ortho-carborane) are known to be of particular interest due to numerous plausible applications, particularly, in medicine, materials science, and advanced technologies. Three principal synthetic strategies resulting in azaheterocyclic carboranes, in which boron-enriched and azaheterocyclic fragments are linked to each other, either directly by means of the C–C bonds or through a short spacer (CH2, CH2S, CH2O, etc.), have been outlined. These synthetic approaches are of general character and can be used both individually and in combination to afford promising organoboron clusters of diverse architectures.1 Introduction2 C–C Cross-Coupling Strategies in the Synthesis of Azaheterocyclic Carboranes3 Carboryne-Based Transformation Strategies4 Condensation Strategies: Reactions of Decaborane B10H14 with Substituted Acetylenes5 Conclusion and Outlook
Funder
Ministry of Education and Science of the Russian Federation
Russian Science Foundation
Subject
Organic Chemistry,Catalysis
Cited by
4 articles.
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1. Reactions of 5-(1,2-Dicarbadodecaboran-1-yl)-3-(2-pyridyl)-1,2,4-triazines with Dienophiles;Russian Journal of General Chemistry;2023-03
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4. Cu(I)-Catalyzed Cycloaddition of Vinylacetylene ortho-Carborane and Arylazides in the Design of 1,2,3-Triazolyl-Modified Vinylcarborane Fluorophores;Organometallics;2020-10-05