Chiral phosphines in nucleophilic organocatalysis-Reference-Cited by-同舟云学术

Chiral phosphines in nucleophilic organocatalysis

Published:2014-09-04 Issue: Volume:10 Page:2089-2121
ISSN:1860-5397
Container-title:Beilstein Journal of Organic Chemistry
language:en
Short-container-title:Beilstein J. Org. Chem.

Author:

Xiao Yumei,Sun Zhanhu,Guo Hongchao,Kwon Ohyun

Abstract

This review discusses the tertiary phosphines possessing various chiral skeletons that have been used in asymmetric nucleophilic organocatalytic reactions, including annulations of allenes, alkynes, and Morita–Baylis–Hillman (MBH) acetates, carbonates, and ketenes with activated alkenes and imines, allylic substitutions of MBH acetates and carbonates, Michael additions, γ-umpolung additions, and acylations of alcohols.

Publisher

Beilstein Institut

Subject

Organic Chemistry

Link

https://www.beilstein-journals.org/bjoc/content/pdf/1860-5397-10-218.pdf

Reference117 articles.

1. Reactions of Electron-Deficient Alkynes and Allenes under Phosphine Catalysis

2. Alkyl Phosphines as Reagents and Catalysts in Organic Synthesis

3. Nucleophilic Phosphine Organocatalysis

4. Synthetic methodology using tertiary phosphines as nucleophilic catalysts

5. Engaging Zwitterions in Carbon−Carbon and Carbon−Nitrogen Bond-Forming Reactions: A Promising Synthetic Strategy

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