Visible-light-mediated selenylation/cyclization reactions of diselenide with acrylimide derivatives: synthesis of selenosubstituted pyrrolidine-2,5-diones

Author:

Han Jia-Hui1,Tian Shi-Yin1,Rao Weidong2ORCID,Shen Shu-Su3,Sheng Daopeng4,Wang Shun-Yi1ORCID

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

2. Key Laboratory of Biomass-based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China

3. School of Environmental Science and Engineering, Suzhou University of Science and Technology, No. 99, Xuefu road, Huqiu district, Suzhou 215009, PR China

4. State Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou, Jiangsu 215123, China

Abstract

We report a visible-light-mediated selenylation/cyclization reaction of selenium radicals generated from diselenides as radical sources with acrylimide derivatives, providing an effective route for the synthesis of symmetrical selenosubstituted pyrrolidine-2,5-diones.

Funder

National Natural Science Foundation of China

Soochow University

Priority Academic Program Development of Jiangsu Higher Education Institutions

Cyrus Tang Foundation

Qinglan Project of Jiangsu Province of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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