Modeling Henry's law and phase separations of water–NaCl–organic mixtures with solvation and ion-pairing-Reference-Cited by-同舟云学术

Modeling Henry's law and phase separations of water–NaCl–organic mixtures with solvation and ion-pairing

Published:2024 Issue:2 Volume:26 Page:749-759
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wilson Aaron D.¹^ORCID,Foo Zi Hao²^ORCID,Jayasinghe Ashini S.³^ORCID,Stetson Caleb¹^ORCID,Lee Hyeonseok¹^ORCID,Rollins Harry W.¹,Deshmukh Akshay²^ORCID,Lienhard John H.²^ORCID

Affiliation:

1. Chemical Separations Group, Idaho National Laboratory, Idaho Falls, ID 83415-2208, USA

2. Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139-4307, USA

3. Analytical Chemistry Group, Idaho National Laboratory, Idaho Falls, ID 83415-2208, USA

Abstract

We used a two-variable speciation-based solution model to correlate VLE (organic Henry’s law coefficient and water activity), SLE (organic-induced salt crystallization), and salt-induced LLE separation of H2O-NaCl-MeCN mixtures.

Funder

Idaho National Laboratory

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP02003G

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