Second ionization constant of sulfuric acid in H2O and D2O from 150 to 300 °C at p = 11.5 MPa using flow AC conductivity-Reference-Cited by-同舟云学术

Second ionization constant of sulfuric acid in H₂O and D₂O from 150 to 300 °C at p = 11.5 MPa using flow AC conductivity

Published:2023 Issue:3 Volume:25 Page:1659-1676
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Conrad Jacy K.¹^ORCID,Arcis Hugues¹^ORCID,Ferguson Jane P.¹^ORCID,Tremaine Peter R.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Guelph, Guelph, ON, N1G 2W1, Canada

Abstract

The ionization constants of bisulfate in light and heavy water at high temperatures were determined from new AC conductivity measurements using a custom-built instrument and the Quint–Viallard conductivity model.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP01761J

Reference79 articles.

1. Aqueous Systems at Elevated Temperatures and Pressures. Physical Chemistry in Water, Steam, and Hydrothermal Solutions , ed. D. A. Palmer , R. Fernández-Prini and A. H. Harvey , Elsevier Ltd , London, UK , 2004

2. P. M.Laughton and R. E.Robertson , Solvent Isotope Effect for Equilibria and Reactions , in Solute-Solvent Interactions , ed. J. F. Coetzee and C. D. Ritchie , Marcel Dekker Inc ., 1969

3. Isotope Effects in Deuterium Oxide Solution. I. Acid-Base Equilibria

4. A formula for correlating p K a values determined in D 2 O and H 2 O

5. THE SECOND DISSOCIATION CONSTANT OF DEUTERIOSULFURIC ACID FROM 25 TO 225°

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Revised Parameters for the IAPWS Formulation for the Ionization Constant of Water Over a Wide Range of Temperatures and Densities, Including Near-Critical Conditions;Journal of Physical and Chemical Reference Data;2024-05-23

2. Comprehensive quantum calculation of the first dielectric virial coefficient of water;The Journal of Chemical Physics;2024-01-12

3. First Ionization Constant of Phosphoric Acid and of Acetic Acid in H2O and D2O from T = 373 K to 573 K at p = 11.5 and 20 MPa by AC Conductivity Methods;Journal of Solution Chemistry;2023-06-21

4. Critical Review of Transport Properties of HCl, KOH, and NaOH in High Temperature Water and Correlations for Transport Properties of H3O+ and OH−;Journal of Physical and Chemical Reference Data;2023-05-17

5. Reactions of Nickel Ions in Water Radiolysis up to 300 °C;The Journal of Physical Chemistry B;2023-03-16