Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH3, N2H4, H2O, H2)-Reference-Cited by-同舟云学术

Heavy metalla vinyl-cations show metal–Lewis acid cooperativity in reaction with small molecules (NH₃, N₂H₄, H₂O, H₂)

Published:2023 Issue:3 Volume:14 Page:514-524
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Auer Maximilian¹,Bolten Janina¹,Eichele Klaus¹,Schubert Hartmut¹,Sindlinger Christian P.²^ORCID,Wesemann Lars¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie, Auf der Morgenstelle 18, 72076 Tübingen, Germany

2. Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

Abstract

Tetrylidinium–iridium cations [ArE = IrHL3]+ (E = Ge, Sn) show a vinyl-cation type bonding situation and are highly reactive electrophiles acting as a cooperative metal–ligand Lewis acid enabling 1,2-addition of NH3, N2H4, H2O, HCl and H2.

Funder

Fonds der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05620H

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