Rectifying interphases for preventing Li dendrite propagation in solid-state electrolytes

Author:

Yao Xuhui12,Lu Xuekun34,Zhou Yundong2ORCID,Šamořil Tomáš5,Bi Jinxin1,Masteghin Mateus G.1ORCID,Zhang Huixing2,Askew Leslie1,Kim JeongWon6ORCID,Xiong Fangyu7,Wang Jianan8ORCID,Cox David C.1,Sui Tan29,Gilmore Ian2,Silva S. Ravi P.1ORCID,Mai Liqiang7ORCID,Hinds Gareth2ORCID,Shearing Paul R.3ORCID,Park Juyeon2,Zhao Yunlong12ORCID

Affiliation:

1. Advanced Technology Institute, University of Surrey, Guildford, Surrey, GU2 7XH, UK

2. National Physical Laboratory, Teddington, Middlesex, TW11 0LW, UK

3. Electrochemical Innovation Lab, Department of Chemical Engineering, University College London, London, WC1E 7JE, UK

4. School of Engineering and Materials Science, Queen Mary University of London, London, E1 4NS, UK

5. TESCAN ORSAY HOLDING, a.s., Libušina tř. 21, Brno, 623 00, Czech Republic

6. Korea Research Institute of Standards and Science, 267 Gajeong-ro, Daejeon, 3411305-600, Republic of Korea

7. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China

8. Department of Environmental Science and Engineering, Xi’an Jiaotong University, Xi’an, 710049, China

9. School of Mechanical Engineering Sciences, University of Surrey, Guildford, Surrey, GU2 7XH, UK

Abstract

The concept of asymmetric electronic conductance is explored in solid-state batteries and realised by a p–n junction interphase, enabling dynamic dendrite-free operation via slow reductive generation and rapid oxidative elimination.

Funder

Royal Society

Engineering and Physical Sciences Research Council

Department for Business, Energy and Industrial Strategy, UK Government

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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