Water-mediated one-pot multi-step synthesis of chiral 1,3-diarylpropan-1-ols by the asymmetric hydrofunctionalisation of simple alkynes-Reference-Cited by-同舟云学术

Water-mediated one-pot multi-step synthesis of chiral 1,3-diarylpropan-1-ols by the asymmetric hydrofunctionalisation of simple alkynes

Published:2024 Issue:7 Volume:26 Page:4074-4078
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Yu Pinke¹,Liu Qixing¹,Zuo Linhong¹,Zhang Xumu²^ORCID,Yin Congcong¹,Zhou Haifeng¹^ORCID

Affiliation:

1. Hubei Key Laboratory of Natural Products Research and Development, College of Biological and Pharmaceutical Sciences, China Three Gorges University, 443002, Yichang, China

2. Department of Chemistry, Academy for Advanced Interdisciplinary Studies and Shenzhen Grubbs Institute, Southern University of Science and Technology, Shenzhen 518055, P. R. China

Abstract

An enantioselective hydration–condensation-asymmetric transfer hydrogenation cascade process of simple alkynes and aldehydes in only water to prepare chiral 1,3-diarylpropan-1-ols has been developed.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D3GC04945K

Reference50 articles.

1. Copper(ii)-catalyzed enantioselective hydrosilylation of halo-substituted alkyl aryl and heteroaryl ketones: asymmetric synthesis of (R)-fluoxetine and (S)-duloxetine

2. Development of a Biocatalytic Process as an Alternative to the (−)-DIP-Cl-Mediated Asymmetric Reduction of a Key Intermediate of Montelukast

3. Diaryl hydroxylamines as pan or dual inhibitors of indoleamine 2,3-dioxygenase-1, indoleamine 2,3-dioxygenase-2 and tryptophan dioxygenase

4. Palladium-catalyzed asymmetric hydrogenation of simple ketones activated by Brønsted acids

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