Generalizable, tunable control of divalent cation solvation structure <i>via</i> mixed anion contact ion pair formation-Reference-Cited by-同舟云学术

Generalizable, tunable control of divalent cation solvation structure via mixed anion contact ion pair formation

Published:2024 Issue:11 Volume:12 Page:6768-6776
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Lavan Sydney N.¹²³^ORCID,Ilic Stefan¹²³,Viswanath Shashwat¹³,Jain Akash¹³^ORCID,Assary Rajeev S.¹²³^ORCID,Connell Justin G.¹²³^ORCID

Affiliation:

1. Joint Center for Energy Storage Research, Argonne National Laboratory, Lemont, IL 60439, USA

2. Center for Steel Electrification by Electrosynthesis, Argonne National Laboratory, Lemont, IL 60439, USA

3. Materials Science Division, Argonne National Laboratory, Lemont, IL 60439, USA

Abstract

Multi-anion electrolytes form mixed anion contact ion pairs (CIPs), even when the constituent anions do not form CIPs in isolation. Mixed anion CIPs are shown to be general for divalent cations, and their relative fraction is tunable by composition.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA07613J

Reference32 articles.

1. Energy storage emerging: A perspective from the Joint Center for Energy Storage Research

2. Promises and Challenges of Next-Generation “Beyond Li-ion” Batteries for Electric Vehicles and Grid Decarbonization

3. Current status and future directions of multivalent metal-ion batteries

4. Tuning the Reversibility of Mg Anodes via Controlled Surface Passivation by H2O/Cl– in Organic Electrolytes

5. Water or Anion? Uncovering the Zn2+ Solvation Environment in Mixed Zn(TFSI)2 and LiTFSI Water-in-Salt Electrolytes

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