Phase stability and charge compensation in disordered rock salt compounds based on nickel and titanium-Reference-Cited by-同舟云学术

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Phase stability and charge compensation in disordered rock salt compounds based on nickel and titanium

Published:2024 Issue:26 Volume:12 Page:15731-15743
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Reitano Agnese¹²,Kunz Sylvia¹²,Xu Mingfeng¹²,Suard Emmanuelle³^ORCID,Bianchini Matteo¹²^ORCID

Affiliation:

1. Department of Chemistry, Universität Bayreuth, Universitätsstrasse 30, 95447 Bayreuth, Germany

2. Bavarian Center for Battery Technology (BayBatt), Universität Bayreuth, Weiherstrasse 26, 95448 Bayreuth, Germany

3. Institut Laue-Langevin, Avenue des Martyrs, 38042 Grenoble Cedex 9, France

Abstract

The synthesis of Ni/Ti disordered rock salt compounds (DRX) features the fast formation of a layered phase before the DRX structure becomes favored by entropy. Electrochemically the compounds exhibit significant structural and electronic hysteresis.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D4TA02265C

Reference54 articles.

1. Ultimate Limits to Intercalation Reactions for Lithium Batteries

2. An Overview of Cation-Disordered Lithium-Excess Rocksalt Cathodes

3. Positive Electrode Materials for Li-Ion and Li-Batteries

4. There and Back Again—The Journey of LiNiO 2 as a Cathode Active Material

5. An in situ structural study on the synthesis and decomposition of LiNiO2

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