Stereoselective synthesis of unnatural α-amino acid derivatives through photoredox catalysis

Author:

Shatskiy Andrey12345ORCID,Axelsson Anton12345,Stepanova Elena V.678910ORCID,Liu Jian-Quan12345ORCID,Temerdashev Azamat Z.1112138ORCID,Kore Bhushan P.142345,Blomkvist Björn12345,Gardner James M.142345ORCID,Dinér Peter12345ORCID,Kärkäs Markus D.12345ORCID

Affiliation:

1. Division of Organic Chemistry

2. Department of Chemistry

3. KTH Royal Institute of Technology

4. Stockholm

5. Sweden

6. Tomsk Polytechnic University

7. 634050 Tomsk

8. Russia

9. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

10. 119991 Moscow

11. Department of Analytical Chemistry

12. Kuban State University

13. 350040 Krasnodar

14. Division of Applied Physical Chemistry

Abstract

A protocol for stereoselective C-radical addition to a chiral glyoxylate-derived N-sulfinyl imine was developed through visible light-promoted photoredox catalysis, providing a convenient method for the synthesis of unnatural α-amino acids.

Funder

Svenska Forskningsrådet Formas

Wenner-Gren Stiftelserna

Vetenskapsrådet

Ministry of Education and Science of the Russian Federation

Carl Tryggers Stiftelse för Vetenskaplig Forskning

Magnus Bergvalls Stiftelse

Kungliga Tekniska Högskolan

Tomsk Polytechnic University

Stiftelsen Olle Engkvist Byggmästare

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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