Distinct electronic structures and bonding interactions in inverse-sandwich samarium and ytterbium biphenyl complexes-Reference-Cited by-同舟云学术

Distinct electronic structures and bonding interactions in inverse-sandwich samarium and ytterbium biphenyl complexes

Published:2021 Issue:1 Volume:12 Page:227-238
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Xiao Yuyuan¹^ORCID,Zhao Xiao-Kun²^ORCID,Wu Tianpin³,Miller Jeffrey T.³,Hu Han-Shi²^ORCID,Li Jun²^ORCID,Huang Wenliang¹^ORCID,Diaconescu Paula L.⁴^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Material Chemistry and Application, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

2. Department of Chemistry and Key Laboratory of Organic Optoelectronics & Molecular Engineering of the Ministry of Education, Tsinghua University, Beijing 100084, P. R. China

3. Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, USA

4. Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, USA

Abstract

Inverse-sandwich samarium and ytterbium biphenyl complexes were synthesized and characterized by X-ray crystallography. Combined experimental and computational studies indicated that they have distinct electronic structures and bonding interactions.

Funder

Peking University

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC03555F

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