Reversible dissociation of singly-bonded (C60−)2 dimers in (MV˙+)2(C60−)2·solvent salt containing paramagnetic methyl viologen MV˙+ radical cations-Reference-Cited by-同舟云学术

Reversible dissociation of singly-bonded (C60−)2 dimers in (MV˙+)2(C60−)2·solvent salt containing paramagnetic methyl viologen MV˙+ radical cations

Published:2021 Issue:3 Volume:45 Page:1163-1167
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Konarev Dmitri V.¹²³^ORCID,Khasanov Salavat S.⁴²³,Obraztsov Oleg A.⁴²³^ORCID,Otsuka Akihiro⁵⁶⁷⁸⁹^ORCID,Yamochi Hideki⁵⁶⁷⁸⁹^ORCID,Kitagawa Hiroshi⁵⁶⁷⁸⁹^ORCID,Lyubovskaya Rimma N.¹²³

Affiliation:

1. Institute of Problems of Chemical Physics RAS

2. Chernogolovka

3. Russia

4. Institute of Solid State Physics RAS

5. Division of Chemistry

6. Graduate School of Science

7. Kyoto University

8. Sakyo-ku

9. Japan

Abstract

Interaction of MV⁰ with C₆₀ produces salt (MV˙⁺)₂(C₆₀⁻)₂⋅solvent (1) containing singly-bonded (C₆₀⁻)₂ dimers dissociated at 235–375 K. There is exchange interaction between MV˙⁺ and C₆₀˙⁻ in the monomeric phase which is switched off in the dimeric phase.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D0NJ05076H

Reference28 articles.

1. Organic Molecular Soft Ferromagnetism in a Fullerene C 60

2. Orientational and Magnetic Ordering of Buckyballs in TDAE-C 60

3. Origin of ferromagnetic exchange interactions in a fullerene–organic compound

4. Polymeric fullerene chains in RbC60 and KC60

5. A Two-Dimensional Organic Metal Based on Fullerene

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