Efficient bromination of olefins, alkynes, and ketones with dimethyl sulfoxide and hydrobromic acid

Author:

Song Song12324,Li Xinwei12324,Sun Xiang12324,Yuan Yizhi12324,Jiao Ning12324

Affiliation:

1. State Key Laboratory of Natural and Biomimetic Drugs

2. Peking University

3. School of Pharmaceutical Sciences

4. Beijing 100191

Abstract

An efficient approach for the bromination of olefins, alkynes and ketones by using the simple DMSO/HBr system has been developed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference72 articles.

1. Organic Bromine and Iodine Compounds, in The Handbook of Environmental Chemistry, ed. A. H. Neilson, Springer, Heidelberg, Berlin, 2003

2. Ullmann's Encyclopedia of Industrial Chemistry: Bromine Compounds, ed. M. J. Dagani, H. J. Barda, T. J. Benya and D. C. Sanders, Wiley-VCH, Weinheim, 2002

3. Triphenylphosphine oxide-catalyzed stereoselective poly- and dibromination of unsaturated compounds

4. Halocarbocyclization versus dihalogenation: substituent directed iodine(iii) catalyzed halogenations

5. N-Bromosuccinimide–carboxylic acid combination: mild and efficient access to dibromination of unsaturated carbonyl compounds

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