Kinetically controlled synthesis of two-dimensional Zr/Hf metal–organic framework nanosheets via a modulated hydrothermal approach

Author:

Hu Zhigang123ORCID,Mahdi Ezwan Mahmoud4567,Peng Yongwu123,Qian Yuhong123,Zhang Bin123,Yan Ning123ORCID,Yuan Daqiang89101112ORCID,Tan Jin-Chong4567ORCID,Zhao Dan123ORCID

Affiliation:

1. Department of Chemical & Biomolecular Engineering

2. National University of Singapore

3. Singapore

4. Department of Engineering Science

5. University of Oxford

6. Oxford OX1 3PJ

7. UK

8. State Key Laboratory of Structural Chemistry

9. Fujian Institute of Research on the Structure of Matter

10. Chinese Academy of Sciences

11. Fuzhou

12. China

Abstract

We describe a surfactant-free bottom-up synthesis of 2D stable MOF nanosheets, NUS-8(Zr or Hf), via the modulated hydrothermal (MHT) approach. These 2D NUS-8 nanosheets demonstrate several prevailing advantages including superior chemical/thermal stabilities and enzyme-specific catalytic activities toward thioether oxidation into sulfones.

Funder

Ministry of Education - Singapore

National University of Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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