Polymorphism and physical properties of pure and lead-doped monoclinic Sm<sub>2</sub>MoO<sub>6</sub> oxymolybdates-Reference-Cited by-同舟云学术

Polymorphism and physical properties of pure and lead-doped monoclinic Sm₂MoO₆ oxymolybdates

Published:2024 Issue:25 Volume:26 Page:3424-3430
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Orlova Ekaterina I.¹²^ORCID,Kostanyan Leon K.³,Trukhacheva Maria P.¹²^ORCID,Sorokin Timofei A.¹^ORCID,Baldin Egor D.⁴^ORCID,Kharitonova Elena P.¹²,Lyskov Nikolay V.⁵⁶,Yapaskurt Vasiliy O.⁷,Alekseeva Olga A.¹,Voronkova Valentina I.²

Affiliation:

1. Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”, Leninskii Prospekt 59, Moscow, 119333, Russian Federation

2. Faculty of Physics, Lomonosov Moscow State University, GSP-1, Leninskie Gory, Moscow, 119991, Russian Federation

3. Department of Chemistry, Lomonosov Moscow State University, GSP-1, Leninskie Gory, Moscow, 119991, Russian Federation

4. N. N. Semenov Federal Research Center For Chemical Physics RAS, Kosygina 4, Moscow, 119991, Russian Federation

5. Federal Research Center for Problems of Chemical Physics and Medical Chemistry of the Russian Academy of Sciences, Acad. Semenov av. 1, Chernogolovka, 142432, Russian Federation

6. HSE University, ul. Myasnitskaya 20, 101000 Moscow, Russian Federation

7. Department of Geology, Lomonosov Moscow State University, GSP-1, Leninskie Gory, Moscow, 119991, Russian Federation

Abstract

Lead-doped samarium Sm2MoO6 oxymolybdate has been prepared in air for the first time. Doping with Pb significantly increases the compound ionic conductivity, which reaches 10−3 S cm−1 at 900 °C.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CE/D4CE00437J

Reference26 articles.

1. Dilanthanide molybdates and tungstates Ln2MO6

2. Ln2MoO6-type rare earth molybdates—Preparation and lattice parameters

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4. Evaluation of the role played by praseodymium molybdates in Pr6O11–MoO3 catalysts for the selective oxidation of isobutene to methacrolein

5. La₂MoO₆ as an Effective Catalyst for the Cathode Reactions of Lithium–Sulfur Batteries