Organic transformation of lignin into mussel-inspired glues: next-generation 2K adhesive for setting corals under saltwater

Author:

Choi Ching-Yi1ORCID,Lossada Francisco1,Walter Keven1,Fleck-Kunde Tom1,Behrens Sascha2,Meinelt Thomas2,Falkenhagen Jana3ORCID,Hiller Matthias4,Oschkinat Hartmut4,Dallmann André1ORCID,Taden Andreas5,Börner Hans G.1ORCID

Affiliation:

1. Humboldt-Universität zu Berlin, Department of Chemistry, Laboratory for Organic Synthesis of Functional Systems, Brook-Taylor Straße 2, 12489 Berlin, Germany

2. Institute of Freshwater Ecology and Inland Fisheries, Department of Ecophysiology and Aquaculture, Müggelseedamm 301, 12587 Berlin, Germany

3. Bundesanstalt für Materialforschung und -prüfung, BAM, Department of Materials Chemistry, Richard-Willstätter-Straße 11, 12489 Berlin, Germany

4. Leibniz-Forschungsinstitut für Molekulare Pharmakologie, FMP, Department of NMR assisted structural biology, Robert-Rössle-Straße 10, 13125 Berlin, Germany

5. Henkel, Adhesives Technologies, Düsseldorf, Germany

Abstract

The generation of quinones in activated lignin allows crosslinking with multi-thiols via thiol-catechol-connectivities (TCCs), leading to a high-performance 2K adhesive that tolerates seawater and is biofriendly and useful for setting corals.

Funder

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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