Photoexcitation dynamics of bromodiphenyl ethers in acetonitrile-d<sub>3</sub> studied by femtosecond time-resolved infrared spectroscopy-Reference-Cited by-同舟云学术

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Photoexcitation dynamics of bromodiphenyl ethers in acetonitrile-d₃ studied by femtosecond time-resolved infrared spectroscopy

Published:2022 Issue:16 Volume:24 Page:9203-9212
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Jung Jisik¹^ORCID,Shin Juhyang¹^ORCID,Dzhaparova Alina¹^ORCID,Park Jin Kyoon¹^ORCID,Lim Manho¹^ORCID

Affiliation:

1. Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University, Busan 46241, Korea

Abstract

Photoexcitation of 3- and 4-bromodiphenyl ethers in CD3CN by 267 nm photon immediately dissociates Br producing solvent-bound diphenyl ether (DE) radical, which further reacts producing cyano-DE or deuterated-DE with an efficiency of 22–33%.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00063F

Reference54 articles.

1. Brominated Organic Micropollutants—Igniting the Flame Retardant Issue

2. Polybrominated diphenyl ether (PBDE) flame retardants

3. Global Historical Stocks and Emissions of PBDEs

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