Activation of non-polar bonds by an electron-rich gallagermylene-Reference-Cited by-同舟云学术

Activation of non-polar bonds by an electron-rich gallagermylene

Published:2024 Issue:21 Volume:60 Page:2902-2905
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bücker Anna¹,Gehlhaar Alexander¹,Wölper Christoph¹,Schulz Stephan¹²^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, University of Duisburg-Essen, Essen 45117, Germany

2. Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Duisburg 47057, Germany

Abstract

The electron-rich acyclic germylene LGa(μ–Cl)GeArMes (1) activates unpolar bonds as is shown in oxidative addition reactions with H2 and P4, yielding L(Cl)GaGe(H)2ArMes (2) and L(Cl)Ga(P4)GeArMes (3).

Funder

Universität Duisburg-Essen

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC06223F

Reference40 articles.

1. Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis

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3. Main-group elements as transition metals

4. Oxidative Addition and Reductive Elimination at Main-Group Element Centers

5. Low-valent group 14 element hydride chemistry: towards catalysis

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