Ligand-free reductive coupling of aldehydes with 1,3-dienes using a sulfur-modified Au-supported nickel nanoparticle catalyst

Author:

Ohta Ryosuke1,Shio Yasunori1,Akiyama Toshiki1ORCID,Yamada Makito1,Harada Kazuo1ORCID,Arisawa Mitsuhiro1ORCID

Affiliation:

1. Graduate School of Pharmaceutical Sciences, Osaka University, Suita, Osaka, 565-0871, Japan

Abstract

Regio- and stereoselective homoallylation reaction of aldehydes with 1,3-dienes using a Ni NP catalyst to afford homoallylated alcohols.

Funder

Japan Society for the Promotion of Science

JST, Core Research for Evolutional Science and Technology

Japan Agency for Medical Research and Development

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference56 articles.

1. Modern Organonickel Chemistry , ed. Y. Tamaru , Wiley-VCH , Weinheim , 2005

2. Metal Catalyzed Reductive C–C Bond Formation , ed. M. J. Krische , Topics in Current Chemistry, Springer-Verlag , Berlin, Heidelberg , 2007 , vol. 279

3. Novel Stereoselective Cyclization via .pi.-Allylnickel Complex Generated from 1,3-Diene and Hydride Nickel Complex

4. Nickel-catalyzed regio- and stereoselective synthesis of homoallylic alcohol derivatives from dienes and aldehydes

5. Further Studies on Nickel-Promoted or -Catalyzed Cyclization of 1,3-Diene and a Tethered Carbonyl Group

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