A charge neutral iron(ii) complex with an above room temperature spin crossover (SCO) and hysteresis loop

Author:

Senthil Kumar Kuppusamy1234,Šalitroš Ivan56789,Heinrich Benoît1234,Fuhr Olaf10111213,Ruben Mario123410

Affiliation:

1. Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS)

2. CNRS-Université de Strasbourg

3. 67034 Strasbourg cedex 2

4. France

5. Institute of Inorganic Chemistry

6. Technology and Materials

7. Faculty of Chemical and Food Technology

8. Slovak University of Technology

9. Bratislava

10. Institute of Nanotechnology

11. Karlsruhe Institute of Technology (KIT)

12. Eggenstein-Leopoldshafen

13. Germany

Abstract

A luminescent charge neutral Fe(ii) complex [Fe(L1)2] with above room temperature hysteretic spin crossover (SCO) is reported; a phase transition is associated with SCO as inferred from thermal and SAXS studies.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Reference75 articles.

1. Spin-Crossover Materials: Properties and Applications, ed. M. A. Halcrow, Wiley, Chichester, 2013

2. Spin-Transition Polymers: From Molecular Materials Toward Memory Devices

3. Thermal, pressure and light switchable spin-crossover materials

4. V. Ksenofontov , A. B.Gaspar and P.Gütlich, in Spin Crossover in Transition Metal Compounds, ed. P. Gütlich and H. A. Goodwin, Topics in Current Chemistry, 2004, 235, pp. 39–66

5. Spin Crossover in a Supramolecular Fe4II [2×2] Grid Triggered by Temperature, Pressure, and Light

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