Fluorine-rich modification of self-extinguishable lithium-ion battery separators using cross-linking networks of chemically functionalized PVDF terpolymers for highly enhanced electrolyte affinity and thermal–mechanical stability

Author:

Park Jaewon1,Kwon Young Je1,Yun Jeongsik2ORCID,Bae Ji Woo1,Lee Min Jeong1,Zhang Kaiyun1,Kim Se Hun1,Baeg Kang-Jun3ORCID,Lee Jin Hong4ORCID,Cho Kie Yong1ORCID

Affiliation:

1. Department of Industrial Chemistry, Pukyong National University, 45 Yongso-Ro, Nam-Gu, Busan 48513, Republic of Korea

2. Department of Energy and Chemical Engineering, Incheon National University, 119 Academy-ro, Yeonsu-gu, Incheon 22012, Republic of Korea

3. Department of Nanotechnology Engineering, Pukyong National University, 45, Yongso-ro, Nam-gu, Busan, 48513, Republic of Korea

4. School of Chemical Engineering, Pusan National University, Busan 46421, Republic of Korea

Abstract

Thermal instability of polypropylene separators (PPSs) threatens the safe battery operation. A double bond-containing polyvinylidene fluoride (DPVDF)-coated PPS (DPS) and the subsequent crosslinking (DPSX) demonstrate an instant fire extinguishing feature and high thermal stability.

Funder

National Research Foundation of Korea

Ministry of Trade, Industry and Energy

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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