Absorption spectroscopy for the quantitative prediction of lanthanide concentrations in the 3LiCl–2CsCl eutectic at 723 K-Reference-Cited by-同舟云学术

Absorption spectroscopy for the quantitative prediction of lanthanide concentrations in the 3LiCl–2CsCl eutectic at 723 K

Published:2016 Issue:43 Volume:8 Page:7731-7738
ISSN:1759-9660
Container-title:Analytical Methods
language:en
Short-container-title:Anal. Methods

Author:

Schroll Cynthia A.¹²³⁴,Lines Amanda M.⁵⁶⁷⁴,Heineman William R.¹²³⁴,Bryan Samuel A.⁵⁶⁷⁴

Affiliation:

1. Department of Chemistry

2. University of Cincinnati

3. Cincinnati

4. USA

5. Energy and Environment Directorate

6. Pacific Northwest National Laboratory

7. Richland

Abstract

The absorption spectra of single-component mixtures of six lanthanide chloride salts were obtained in the molten salt eutectic 3LiCl–2CsCl at 723 K, and used to build multivariate regression models to predict concentrations of multi-component mixtures of these metals in solution.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Chemical Engineering,Analytical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/AY/C6AY01520D

Reference34 articles.

1. Measurement of standard potentials of actinides (U,Np,Pu,Am) in LiCl–KCl eutectic salt and separation of actinides from rare earths by electrorefining

2. Determination of uranium and rare-earth metals separation coefficients in LiCl–KCl melt by electrochemical transient techniques

3. Development of quantitative analytical methods for the control of actinides in a pyrochemical partitioning process