Influence of the phonon-bottleneck effect and low-energy vibrational modes on the slow spin-phonon relaxation in Kramers-ions-based Cu(<scp>ii</scp>) and Co(<scp>ii</scp>) complexes with 4-amino-3,5-bis-(pyridin-2-yl)-1,2,4-triazole and dicyanamide-Reference-Cited by-同舟云学术

Influence of the phonon-bottleneck effect and low-energy vibrational modes on the slow spin-phonon relaxation in Kramers-ions-based Cu(ii) and Co(ii) complexes with 4-amino-3,5-bis-(pyridin-2-yl)-1,2,4-triazole and dicyanamide

Published:2024 Issue:16 Volume:53 Page:6950-6964
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Potočňák Ivan¹^ORCID,Bukrynov Oleksandr²,Kliuikov Andrii³⁴^ORCID,Holub Mariia³⁵^ORCID,Vitushkina Svitlana²⁶,Samoľová Erika⁷^ORCID,Čižmár Erik³^ORCID,Váhovská Lucia⁸^ORCID

Affiliation:

1. P. J. Šafárik University in Košice, Faculty of Science, Institute of Chemistry, Department of Inorganic Chemistry, Moyzesova 11, SK-041 54 Košice, Slovakia

2. V. N. Karazin Kharkiv National University, Faculty of Chemistry, Department of Applied Chemistry, Svobody sq. 4, UA-61022 Kharkiv, Ukraine

3. P. J. Šafárik University in Košice, Faculty of Science, Institute of Physics, Park Angelinum 9, SK-041 54 Košice, Slovakia

4. Slovak Metrological Institute, Karloveská 63, SK-842 55 Bratislava, Slovakia

5. Synchrotron SOLEIL, L'Orme des Merisiers, Départementale 128, FR-91190 Saint-Aubin, France

6. Institute of Experimental Physics of the Slovak Academy of Sciences, Department of Materials Physics, Watsonova 47, SK-040 01 Košice, Slovakia

7. Institute of Physics of the Czech Academy of Sciences, Na Slovance 2, CZ-182 21 Prague 8, Czech Republic

8. University of Veterinary Medicine and Pharmacy in Košice, Department of Chemistry, Biochemistry and Biophysics, Komenského 73, SK-041 84 Košice, Slovakia

Abstract

Two new complexes, [Cu(abpt)2(dca)2] and [Co(abpt)2(dca)2] (abpt = 4-amino-3,5-bis-(pyridin-2-yl)-1,2,4-triazole; dca = dicyanamide), have been prepared and magneto-structurally characterised.

Funder

Agentúra na Podporu Výskumu a Vývoja

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

European Commission

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00219A

Reference132 articles.

1. Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands

2. Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials

3. Synthesis and co-ordination chemistry of a novel dinucleating chelating triazole ligand. The crystal structure of bis-µ-[4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole-N′, µ-N1,µ-N2,N″,]-bis[aquachloro-nickel(II)] dichloride tetrahydrate

4. Synthesis and properties of isostructural transition-metal (copper, nickel, cobalt, and iron) compounds with 7,7',8,8'-tetracyanoquinodimethanide(1-) in an unusual monodentate coordination mode: crystal structure of bis(3,5-bis(pyridin-2-yl)-4-amino-1,2,4-triazole)bis(7,7',8,8'-tetracyanoquinodimethanido)copper(II)

5. Synthesis, structure and magnetic properties of mono-, dinuclear and polymeric compounds of transition metals with 4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Structural, optical and magnetic properties of a new metal–organic Co^II-based complex;RSC Advances;2024

2. Reciprocating thermal behaviour in a series of 7-coordinate Mn(ii) and Co(ii) complexes;Journal of Materials Chemistry C;2024