Hexane isomers separation on an isoreticular series of microporous Zr carboxylate metal organic frameworks

Author:

Henrique Adriano12345ORCID,Maity Tanmoy6789,Zhao Hengli1011121314,Brântuas Pedro F.1516171819ORCID,Rodrigues Alírio E.12345ORCID,Nouar Farid2021221123,Ghoufi Aziz1011121314ORCID,Maurin Guillaume2425112627,Silva José A. C.1516171819,Serre Christian2021221123ORCID

Affiliation:

1. Laboratory of Separation and Reaction Engineering

2. Laboratory of Catalysis and Materials (LSRE/LCM)

3. Department of Chemical Engineering

4. Faculty of Engineering University of Porto

5. 4200-465 Porto

6. Solid State and Structural Chemistry Unit

7. Indian Institute of Science

8. Bangalore

9. India

10. Univ. Rennes

11. CNRS

12. IPR (Institut de Physique de Rennes) – UMR 6251

13. F-35000 Rennes

14. France

15. Centro de Investigação de Montanha (CIMO)

16. Instituto Politécnico de Bragança

17. Campus de Santa Apolónia

18. 5300-253 Bragança

19. Portugal

20. Institut des Matériaux Poreux de Paris

21. Ecole Normale Supérieure de Paris

22. ESPCI Paris

23. PSL University

24. ICGM

25. Univ. Montpellier

26. ENSCM

27. Montpellier

Abstract

The microporous MOF MIL-140B can separate hexane isomers according to the degree of branching, linear >mono-branched >di-branched, with a remarkably high selectivity up to 10 at 343 K. GCMC simulations confirm the origins of the molecular separation.

Funder

Agence Nationale de la Recherche

Fundação para a Ciência e a Tecnologia

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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