Shape-controlled synthesis and self-assembly of highly uniform upconverting calcium fluoride nanocrystals

Author:

Paik Taejong12ORCID,Greybush Nicholas J.3,Najmr Stan4,Woo Ho Young1,Hong Seong Vin1,Kim Seung Hyeon2,Lee Jennifer D.4ORCID,Kagan Cherie R.345ORCID,Murray Christopher B.34

Affiliation:

1. School of Integrative Engineering, Chung-Ang University, Seoul, 06974, South Korea

2. Department of Intelligent Semiconductor Engineering, Chung-Ang University, Seoul 06974, Republic of Korea

3. Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania, 19104, USA

4. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania, 19104, USA

5. Department of Electrical and Systems Engineering, University of Pennsylvania, Philadelphia, Pennsylvania, 19104, USA

Abstract

A novel synthetic method to tailor the shapes of highly uniform upconverting CaF2 NCs is demonstrated. We investigate the shape-dependent self-assemblies, and size, shape, and dopant composition-dependent upconversion luminescence of CaF2 NCs.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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