High-pressure in situ X-ray absorption fine structure measurements for hydrogenation of CO2 to methanol over Zn-doped ZrO2-Reference-Cited by-同舟云学术

High-pressure in situ X-ray absorption fine structure measurements for hydrogenation of CO₂ to methanol over Zn-doped ZrO₂

Published:2024 Issue: Volume: Page:
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Tada Shohei¹^ORCID,Oshima Kazumasa²^ORCID,Joutsuka Tastuya³^ORCID,Nishijima Masahiko⁴,Kikuchi Ryuji¹^ORCID,Honma Tetsuo⁵^ORCID

Affiliation:

1. Division of Applied Chemistry, Hokkaido University, N13 W8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan

2. Department of Chemical Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

3. Department of Materials Science and Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577, Japan

4. Flexible 3D System Integration Laboratory, Osaka University, 8-1 Mihogaoka, Ibaraki-Shi, Osaka 567-0047, Japan

5. Japan Synchrotron Radiation Research Institute, 468-1, Aramaki Aza Aoba, Aobaku, Sendai, Miyagi 980-8572, Japan

Abstract

During CO2 hydrogenation under pressurised conditions, slight distortions were observed in the Zn structure. Our DFT calculations revealed that the adsorption of CO2 at Zr4+ sites near Zn species can induce these structural distortions.

Funder

Environmental Restoration and Conservation Agency

New Energy and Industrial Technology Development Organization

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CY/D4CY00894D

Reference31 articles.

1. CO2 hydrogenation to high-value products via heterogeneous catalysis

2. Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis

3. Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes

4. Recent advances in ammonia synthesis over ruthenium single-atom-embedded catalysts: A focused review

5. Oxide Solid–Solution Catalysts with Good Redox Properties for Liquid–Phase Aerobic Additive–Free Oxidation: A Review