Copper-catalyzed selective construction of vinyl sulfones employing TosMIC as a C1 synthon and sulfone source-Reference-Cited by-同舟云学术

Copper-catalyzed selective construction of vinyl sulfones employing TosMIC as a C1 synthon and sulfone source

Published:2024 Issue:9 Volume:11 Page:2528-2533
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Cai Qun¹,Si Meng-Jie¹,Shi Xin-Ru¹,Liao Meng¹,Liu Fa-Chuang¹,Wang Min¹,Li Ke-Xin¹,Chen Yong-Ting¹,Wu An-Xin²^ORCID

Affiliation:

1. Key Laboratory of Coal Conversion and New Carbon Materials of Hubei Province, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, P. R. China

2. National Key Laboratory of Green Pesticide, International Joint Research Center for Intelligent Biosensor Technology and Health, Central China Normal University, Wuhan 430079, P. R. China

Abstract

A novel strategy for the selective synthesis of (E)-vinyl sulfone derivatives from p-tosylmethyl isocyanide (TosMIC) and ortho-substituted benzaldehydes has been established.

Funder

National Natural Science Foundation of China

State Key Laboratory of Refractories and Metallurgy

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00049H

Reference52 articles.

1. The chemistry of vinyl sulphones

2. Recent advances in the synthesis of vinyl sulfones

3. t-BuOK-Mediated Reductive Desulfonylation/Dehydrogenation for the Synthesis of 2-Substituted 1,3-Dienes and Their [4+2] Cycloaddition Reactions

4. Catalytic Enantioselective C−C Bond Forming Conjugate Additions with Vinyl Sulfones

5. Enantioselective Organocatalytic Conjugate Addition of Aldehydes to Vinyl Sulfones and Vinyl Phosphonates as Challenging Michael Acceptors