A visible-light-promoted metal-free approach for N–H insertions by using donor/donor diazo precursors-Reference-Cited by-同舟云学术

A visible-light-promoted metal-free approach for N–H insertions by using donor/donor diazo precursors

Published:2024 Issue:8 Volume:26 Page:4600-4608
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhang Yu¹^ORCID,Li Qiannan¹,Wang Ping¹,Wang Jinxin²^ORCID,Lin Jingchuan¹,Xia Dingding¹,Hao Er-Jun³^ORCID,Luan Xin¹^ORCID,Das Shoubhik⁴^ORCID,Zhang Wei-Dong¹²⁵^ORCID

Affiliation:

1. Shanghai Frontiers Science Center for Chinese Medicine Chemical Biology, Institute of Interdisciplinary Integrative Medicine Research, Shanghai University of Traditional Chinese Medicine, No. 1200, Cailun Road, Shanghai 201203, China

2. School of Pharmacy, Second Military Medical University, Shanghai 200433, China

3. Department School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China

4. Department of Chemistry, University of Bayreuth, Bayreuth, Germany

5. Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 100193, China

Abstract

A metal-free and catalyst-free strategy is reported to achieve N–H insertions by coupling N-tosylhydrazones with diverse amines including aminopyridines, anilines, aliphatic amines, and other nucleophiles such as imidazoles and indoles.

Funder

Shanghai Education Development Foundation

Shanghai Municipal Education Commission

National Natural Science Foundation of China

National Basic Research Program of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D3GC04431A

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