Accessing metal-specific orbital interactions in C–H activation with resonant inelastic X-ray scattering-Reference-Cited by-同舟云学术

Accessing metal-specific orbital interactions in C–H activation with resonant inelastic X-ray scattering

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Banerjee Ambar¹^ORCID,Jay Raphael M.¹^ORCID,Leitner Torsten¹,Wang Ru-Pan²^ORCID,Harich Jessica²,Stefanuik Robert¹,Coates Michael R.³^ORCID,Beale Emma V.⁴^ORCID,Kabanova Victoria⁴^ORCID,Kahraman Abdullah⁴,Wach Anna⁴⁵^ORCID,Ozerov Dmitry⁴,Arrell Christopher⁴,Milne Christopher⁶^ORCID,Johnson Philip J. M.⁴^ORCID,Cirelli Claudio⁴^ORCID,Bacellar Camila⁴,Huse Nils²^ORCID,Odelius Michael³^ORCID,Wernet Philippe¹^ORCID

Affiliation:

1. Department of Physics and Astronomy, Uppsala University, 751 20 Uppsala, Sweden

2. Center for Free-Electron Laser Science, Department of Physics, University of Hamburg, 22761 Hamburg, Germany

3. Department of Physics, Stockholm University, AlbaNova University Center, 106 91 Stockholm, Sweden

4. Paul Scherrer Institute, CH-5232 Villigen PSI, Switzerland

5. Institute of Nuclear Physics, Polish Academy of Sciences, PL-31342 Krakow, Poland

6. European XFEL GmbH, 22869 Schenefeld, Germany

Abstract

We propose, using simulated RIXS signatures, a way of spectroscopically accessing the “two-way” charge transfer interactions between the C–H bond and the metal during C–H activation, thereby verifying and motivating orbital correlation diagrams.

Funder

Narodowe Centrum Nauki

Bundesministerium für Bildung und Forschung

Deutsche Forschungsgemeinschaft

Carl Tryggers Stiftelse för Vetenskaplig Forskning

Vetenskapsrådet

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC04388F

Reference57 articles.

1. Large-Scale Selective Functionalization of Alkanes

2. Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

3. Photochemical mechanisms in intermolecular C-H bond activation reactions of organometallic complexes

4. Catalytic Functionalization of Arenes and Alkanes via C−H Bond Activation

5. Addition of Olefins to Aromatic Ketones Catalyzed by Rh(I) Olefin Complexes